Metal cutting tools use cemented carbides like WC-Co (tungsten carbide in cobalt-rich matrix) with different CVD and PVD based coatings to improve the surface hardness, rigidity and wear resistance. These coatings are mainly transition metal nitrides and carbides like TiN, TiC, ZrN, VN, TiCN, TiAlN.
In this application example, TiC/N, and Al2O3 layers on WC-Co layers are mapped with EDS. Fig. 1 shows the focused ion beam (FIB) cross section of the cutting tool edge. Top TiN coating layer is followed by Al2O3/TiN/TiCN/TiN and WC-Co as substrate. With EDS, we could differentiate changes in N composition between TiN, TiCN and TiN layers (Fig. 2). Additionally, ESPRIT analytical software from Bruker is able to deconvolute strongly overlapping Ti and N (Fig. 4) automatically.