AFM Modes

Switching Spectroscopy Piezoresponse Force Microscopy (SS-PFM)

Quantitative ferroelectric hysteresis loop measurement with highest sensitivity and accuracy

Next-Generation Ferroelectric Materials Research with SS-PFM Mode

Switching Spectroscopy Piezoresponse Force Microscopy (SS-PFM) mode enables highly accurate nanoscale characterization of the properties of ferroelectric materials, expanding upon standard Piezoresponse Force Microscopy (PFM) by greatly improving the sensitivity and accuracy of measurements. This mode:

  • Significantly reduces the electrostatic artifacts that can influence signals measured by traditional PFM modes while achieving comparatively higher sensitivity.
  • Provides hyperspectral maps of ferroelectric key parameters, revealing information about the XY heterogeneity of a sample and its correlation with other properties with an otherwise unattainable level of detail.
  • Enables quantification of key parameters of the ferroelectric hysteresis loop and comparison of material performance across instruments, labs, and probes.

Used alone or in conjunction with other AFM operational modes, SS-PFM provides new insights into the material microstructure/polarization switching relationship.

PFM response of a sample with positive electrostrictive constant such as PZT. The sample expands if the polarization of the domain is parallel to an increasing electric field.
Typical clockwise ferroelectric hysteresis loop of a sample with positive electrostrictive constant. Key parameters include coercive biases (V0), nucleation bias (Vc), saturation response (Rs), and remnant response (R0). Each has a positive and negative version (i.e. V0+).

Achieve Higher Sensitivity for Ultimate Low Signal Performance

The signal levels in PFM are generally small, with typical amplitudes <10 pm/V. This is at the limit of what an AFM can detect. To address this, one of two approaches are generally taken:

  1. Increasing the AC stimulation voltage, which would increase the PFM signal, or
  2. Mechanically amplifying the small PFM signal using the contact resonance of the cantilever.

For many samples, arbitrarily increasing the AC stimulation voltage is not a practical approach. Sample domains will flip (poll) if coercive bias is exceeded; the measured amplitude will not be accurate. This is especially true for thin films where the coercive bias is often lower.

Cantilever amplitude (top) and phase (bottom) measured during frequency sweep. Near contact resonance, amplitude is significantly larger and phase lower noise than off-resonance.

To characterize low response ferroelectrics without domain flipping, SS-PFM:

  • Improves the signal-to-noise ratio by applying the AC voltage near the contact resonant frequency of the cantilever and measuring the response.
  • Provides accurate measurements of both amplitude (A) and quality factor (Q) of the resonance to enable quantification of the response (A/Q).
  • Achieves more accurate measurements of A, Q, and phase by using frequency sweeps and lock-in amplifiers to measure response, allowing longer integration times for ultimate low signal performance.

Perform Accurate Hysteresis Loop Measurements

Eliminate Artifacts

Standard PFM allows the measurement of ferroelectric behavior with nanoscale resolution, but measured signals can be influenced by electrostatic forces on the cantilever, as well as ferroelectric response.​ These can cause errors in hysteresis loop quantification, and can even misidentify non-ferrous materials as ferroelectric.


SS-PFM mode provides:

  • Both off-field and on-field loops, separating read and write measurements with SS-PFM scripted spectroscopy.
  • Further mitigation of electrostatic artifacts by acquiring data at different read voltages as well as different write voltages.
  • Unambiguous phase and correct direction of hysteresis loop (and characterization sign of electrostrictive coefficient) with DCUBE-CR-PFM.
Top: The electrostatic force between the cantilever and the sample creates an artifact by influencing the PFM response. Bottom: Using a switching waveform, called the SS-PFM probing waveform, which contains multiple different read voltages, one can compensate for the electrostatic artifact.

Map Ferroelectric Parameters

By collecting and analyzing an array of SS-PFM spectra, it is possible to generate maps of the key piezoelectric parameters, demonstrating the variation in the ferroelectric properties across the XY plane with nanoscale resolution.


SS-PFM delivers:

  • Highly sensitive and repeatable point measurements of the key ferroelectric parameters from the hysteresis loop.
  • Quantitative information—inaccessible via simpler imaging modes—through hyperspectral analysis of script data.
  • Maps of ferroelectric material properties, which can be correlated with properties drawn from other maps (piezoelectric map, chemical map, etc.).
Clockwise, from top: Hysteresis loop in PZT showing key parameters; Map of Vc+ created by collecting spectra at points in a 10x10 matrix; Map of V0+ showing previously polled region.

Avoid Contact Mode for Repeatable Results

Standard PFM operates in contact mode, which is not suitable for samples that are susceptible to damage or displacement by the AFM tip dragging across the sample surface during the scan. Softer probes could partially mitigate this issue, but are more prone to electrostatic artifacts in the PFM measurements.

Like Bruker's unique DCUBE-PFM modes, SS-PFM avoids dragging the tip on the surface. This eliminates the harmful lateral forces that plague conventional contact mode based approaches. When combined with PeakForce Tapping and MIROView for pre-scanning and navigation, contact mode can be avoided completely.


SS-PFM mode supports:

  • Low-impact scans of delicate samples like polymers, fibers, and nanoparticles.
  • Enhanced tip lifetime when working with hard samples.
  • More consistent PFM images without compromising signal measurement accuracy.
Clockwise from left: MIROView canvas with SS-PFM RampScript array on PFM image; DCUBE-PFM image of polymer lamellae; worn tip after use in contact mode.

Ease of Use and Flexibility in Experimental Design and Analysis

Innovation with Advanced Software and Analysis

Bruker's state-of-the-art, easily accessible software and analysis tools provide the flexibility researchers need.

  • Our easy-to-use script generator can create the switching waveform script from seven key parameters. Advanced users can also create unique scripts in XML.
  • Open-source Python-based analysis code enables researchers to see exactly how analysis works and develop innovative approaches to analyzing SS-PFM data.
  • For researchers developing their own electronics, a Signal Access Module (SAM 6) allows hardware access to raw signals and can also provide high voltage for samples with large coercive biases.
Clockwise from top left: Easy-to-use script generator; Python-based analysis code; Signal access module 6; Script editor.

Seamless Integration with the New NanoScope 6 Controller

PFM-type experiments are particularly sensitive to background and crosstalk influences. Integration with the new NanoScope 6 controller reduces these influences, providing highest performance background and crosstalk via optimized lock-in amplifiers and signal routing.

This benefits many AFM operational modes, yet it provides unique advantages for PFM-type modes (like SS-PFM) including:

  • Simpler analysis due to improved signal to noise.
  • Clean, accurate measurements; even with low level signals at high frequencies.
NanoScope 6 Controller display