Different Approaches to Bulk Quantification

On-Demand Session - 69 Minutes

Analysis of Homogeneous Bulk with M4 Tornado

In XRF there are different approaches to the quantification of spectra from bulk samples. Every quantification approach has specific strengths and weaknesses, but the M4 TORNADO's “tool box” of suitable quantification methods allows to have appropriate options when it comes to quantification of non-ideal sample types.

Where for unknown samples the fundamental parameter (FP) approach allows to quantify pretty much any sample spectra from homogeneous bulk materials with reasonable precision, it usually does not consider all tertiary and higher order effects in the sample. The quality of every FP quantification at the end depends on the existing knowledge of the FP parameters specific for each element and potential interelement effects for some combinations of elements. These parameters are better known for some elements than for others. Additionally, not all samples are suitable for a bulk FP quantification. As the FP quantification based on Sherman’s equation assumes the sample to be ideal. Meaning the sample is infinitely large with respect to the probed volume and homogeneous on this scale. Furthermore, the quantification struggles if the sample contains significant amounts of Elements lighter than Sodium (such as Water, CO2, etc.).

Therefore, to improve precision it is recommended either to combine FP quantification approaches with standards (semi-empirical standard supported FP) or to use fully empirical methods such as Lucas-Tooth or even a polynomial calibration (correlating counts with certain sample properties, such as thickness or element concentration) for samples with negligible interelement effects.

The webinar will be rounded off by a 15-minute Q&A session where our experts will answer your questions.

Deconvolution of measured spectra with ppm range traces of a well-known standard.
Simple polynomial calibration using a linear regression for a sample with small amounts of sulfur in an adverse matrix.

Who Should Attend?

  • Quality control specialists assuring composition of metal samples as well as failure analysis in industry and material research laboratories
  • Researchers in R&D


Dr. Roald Tagle

Global Manager Application Science, Bruker Nano Analytics

Dr. Max Buegler

Application Scientist Micro-XRF, Bruker Nano Analytics

Falk Reinhardt

Senior Application Scientist micro-XRF, Bruker Nano Analytics

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