Element distribution mapping of semiconductor nanostructures with X-ray based methods is not always straight forward. The need of nanoscale spatial resolution and X-ray peak overlaps are common challenges when investigating semiconductor materials. Sometimes it can be beneficial to use the SEM instead of expensive TEM tools and time for characterization. The present example shows a high-resolution EDS map of a semiconductor structure acquired in SEM using an annular XFlash® FlatQUAD EDS detector with 4 SDD quadrants arranged with radial symmetry between the specimen and the SEM pole piece. 20 kV accelerating voltage and 220 pA beam current were the measurement conditions. The high sensitivity of the XFlash® QUAD detector allows to achieve better than 10 nm spatial resolution (see Fig. 2) in SEM. Despite strongly overlapping X-ray peaks, silicon (Si) and tungsten (W) can be well distinguished in the map thanks to peak deconvolution models implemented in the Bruker' ESPRIT software (see Fig. 1).